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March Issue |
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Resources |
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by Joseph Orlins and Anne Wehrly
As water pollution threatens our health and environment, we need to implement an expanding array of techniques for its assessment, prevention, and remediation.
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High levels of nutrients can result in blooms of algae, as seen on Alligator Bayou near Baton Rouge, Louisiana.
n the 1890s, entrepreneur William Love sought to establish a model industrial community in the La Salle district of Niagara Falls, New York. The plan included building a canal that tapped water from the Niagara River for a navigable waterway and a hydroelectric power plant. Although work on the canal was begun, a nationwide economic depression and other factors forced abandonment of the project.
By 1920, the land adjacent to the canal was sold and used as a landfill for municipal and industrial wastes. Later purchased by Hooker Chemicals and Plastics Corp., the landfill became a dumping ground for nearly 21,000 tons of mixed chemical wastes before being closed and covered over in the early 1950s. Shortly thereafter, the property was acquired by the Niagara Falls Board of Education, and schools and residences were built on and around the site.
In the ensuing decades, groundwater levels in the area rose, parts of the landfill subsided, large metal drums of waste were uncovered, and toxic chemicals oozed out. All this led to the contamination of surface waters, oily residues in residential basements, corrosion of sump pumps, and noxious odors. Residents began to question if these problems were at the root of an apparent prevalence of birth defects and miscarriages in the neighborhood.
Eventually, in 1978, the area was declared unsafe by the New York State Department of Health, and President Jimmy Carter approved emergency federal assistance. The school located on the landfill site was closed and nearby houses were condemned. State and federal agencies worked together to relocate hundreds of residents and contain or destroy the chemical wastes.
That was the bitter story of Love Canal. Although not the worst environmental disaster in U.S. history, it illustrates the tragic consequences of water pollution.
Water quality standards
n addition to toxic chemical wastes, water pollutants occur in many other forms, including pathogenic microbes (harmful bacteria and viruses), excess fertilizers (containing compounds of phosphorus and nitrogen), and trash floating on streams, lakes, and beaches. Water pollution can also take the form of sediment eroded from stream banks, large blooms of algae, low levels of dissolved oxygen, or abnormally high temperatures (from the discharge of coolant water at power plants).
The United States has seen a growing concern about water pollution since the middle of the twentieth century, as the public recognized that pollutants were adversely affecting human health and rendering lakes
unswimmable, streams unfishable, and rivers flammable. In response, in 1972, Congress passed the Federal Water Pollution Control Act Amendments, later modified and referred to as the Clean Water Act. Its purpose was to "restore and maintain the chemical, physical, and biological integrity of the nation's waters."
The Clean Water Act set the ambitious national goal of completely eliminating the discharge of pollutants into navigable waters by 1985, as well as the interim goal of making water clean enough to sustain fish and wildlife, while being safe for swimming and boating. To achieve these goals, certain standards for water quality were established.
The "designated uses" of every body of water subject to the act must first be identified. Is it a source for drinking water? Is it used for recreation, such as swimming? Does it supply agriculture or industry? Is it a significant habitat for fish and other aquatic life? Thereafter, the water must be tested for pollutants. If it fails to meet the minimum standards for its designated uses, then steps must be taken to limit pollutants entering it, so that it becomes suitable for those uses.
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A technician with the Agricultural Research Service uses an ion chomatograph to determine the concentrations of fertilizer nutrients in samples of drainage water.
On the global level, the fundamental importance of clean water has come into the spotlight. In November 2002, the UN Committee on Economic, Cultural and Social Rights declared access to clean water a human right. Moreover, the United Nations has designated 2003 to be the International Year of Freshwater, with the aim of encouraging sustainable use of freshwater and integrated water resources management.
Here, there, and everywhere
mplementing the Clean Water Act requires clarifying the sources of pollutants. They are divided into two groups: "point sources" and
"nonpoint sources." Point sources correspond to discrete, identifiable locations from which pollutants are emitted. They include factories, wastewater treatment plants, landfills, and underground storage tanks. Water pollution that originates at point sources is usually what is associated with headline-grabbing stories such as those about Love Canal.
Nonpoint sources of pollution are diffuse and therefore harder to control. For instance, rain washes oil, grease, and solid pollutants from streets and parking lots into storm drains that carry them into bays and rivers. Likewise, irrigation and rainwater leach fertilizers, herbicides, and insecticides from farms and lawns and into streams and lakes.
The direct discharge of wastes from point sources into lakes, rivers, and streams is regulated by a permit program known as the National Pollutant Discharge Elimination System
(NPDES). This program, established through the Clean Water Act, is administered by the Environmental Protection Agency (EPA) and authorized states. By regulating the wastes discharged, NPDES has helped reduce point-source pollution dramatically. On the other hand, water pollution in the United States is now mainly from nonpoint sources, as reported by the EPA.
Tragedy at Minamata Bay
The Chisso chemical factory, located on the Japanese island of Kyushu, is believed to have discharged between 70 and 150 tons of methylmercury (an organic form of mercury) into Minamata Bay between 1932 and 1968. The factory, a dominant presence in the region, used the chemical to manufacture acetic acid and vinyl chloride.
Methylmercury is easily absorbed upon ingestion, causing widespread damage to the central nervous system. Symptoms include numbing and unsteadiness of extremities, failure of muscular coordination, and impairment of speech, hearing, and vision. Exposure to high levels of the substance can be fatal. In addition, the effects are magnified for infants exposed to methylmercury through their mo, both before birth and while nursing.
In the 1960s and '70s, it was revealed that thousands of Minamata Bay residents had been exposed to methylmercury. The chemical had been taken up from the bay's waters by its fish and then made its way into the birds, cats, and people who ate the fish. Consequently, methylmercury poisoning came to be called Minamata disease.
Remediation, which took as long as 14 years, involved removing the mercury-filled sediments and containing them on reclaimed land in Minamata Bay. Fish in the bay had such high levels of methylmercury that they had to be prevented from leaving the bay by a huge net, which was in place from 1974 to 1997.
Mercury poisoning has recently appeared in the Amazon basin, where deforestation has led to uncontrolled runoff of natural accumulations of mercury from the soil into rivers and streams. In the United States, testing has revealed that predator fish such as bass and walleye in certain lakes and rivers contain enough mercury to justify warnings against consuming them in large amounts.
--J.O. and A.W.
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In 1991, the U.S. Geological Survey
(USGS, part of the Department of the Interior) began a systematic, long-term program to monitor watersheds. The National Water-Quality Assessment Program
(NAWQA), established to help manage surface and groundwater supplies, has involved the collection and analysis of water quality data in over 50 major river basins and aquifer systems in nearly all 50 states.
The program has encompassed three principal categories of investigation: (1) the current conditions of surface water and groundwater; (2) changes in those conditions over time; and (3) major factors--such as climate, geography, and land use--that affect water quality. For each of these categories, the water and sediment have been tested for such pollutants as pesticides, plant nutrients, volatile organic compounds, and heavy metals.
The NAWQA findings were disturbing. Water quality is most affected in watersheds with highest population density and urban development. In agricultural areas, 95 percent of tested streams and 60 percent of shallow wells contained herbicides, insecticides, or both. In urban areas, 99 percent of tested streams and 50 percent of shallow wells had herbicides, especially those used on lawns and golf courses. Insecticides were found more frequently in urban streams than in agricultural ones.
The study also found large amounts of plant nutrients in water supplies. For instance, 80 percent of agricultural streams and 70 percent of urban streams were found to contain phosphorus at concentrations that exceeded EPA guidelines.
Moreover, in agricultural areas, one out of five well-water samples had nitrate concentrations higher than EPA standards for drinking water. Nitrate contamination can result from nitrogen fertilizers or material from defective septic systems leaching into the groundwater, or it may reflect defects in the wells.
Effects of pollution
ccording to the UN World Water Assessment
Programme, about 2.3 billion people suffer from diseases associated with polluted water, and more than 5 million people die from these illnesses each year. Dysentery, typhoid, cholera, and hepatitis A are some of the ailments that result from ingesting water contaminated with harmful microbes. Other illnesses--such as malaria,
filariasis, yellow fever, and sleeping sickness--are transmitted by vector organisms (such as mosquitoes and tsetse flies) that breed in or live near stagnant, unclean water.
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Testing the effect of simulated rainfall on fresh manure, scientists with the Agricultural Research Service have found that grass strips are highly effective at preventing manure-borne microbes from being washed down a slope and contaminating waters.
A number of chemical contaminants--including DDT, dioxins, polychlorinated biphenyls (PCBs), and heavy metals--are associated with conditions ranging from skin rashes to various cancers and birth defects. Excess nitrate in an infant's drinking water can lead to the "blue baby syndrome"
(methemoglobinemia)--a condition in which the child's digestive system cannot process the nitrate, diminishing the blood's ability to carry adequate concentrations of oxygen.
Besides affecting human health, water pollution has adverse effects on ecosystems. For instance, while moderate amounts of nutrients in surface water are generally not problematic, large quantities of phosphorus and nitrogen compounds can lead to excessive growth of algae and other nuisance species. Known as
eutrophication, this phenomenon reduces the penetration of sunlight through the water; when the plants die and decompose, the body of water is left with odors, bad taste, and reduced levels of dissolved oxygen.
Low levels of dissolved oxygen can kill fish and shellfish. In addition, aquatic weeds can interfere with recreational activities (such as boating and swimming) and can clog intake by industry and municipal systems.
Some pollutants settle to the bottom of streams, lakes, and harbors, where they may remain for many years. For instance, although DDT and PCBs were banned years ago, they are still found in sediments in many urban and rural streams. They occur at levels harmful to wildlife at more than two-thirds of the urban sites tested.
Prevention and remediation
s the old saying goes, an ounce of prevention is worth a pound of cure. This is especially true when it comes to controlling water pollution. Several important steps taken since the passage of the Clean Water Act have made surface waters today cleaner in many ways than they were 30 years ago.
For example, industrial wastes are mandated to be neutralized or broken down before being discharged to streams, lakes, and harbors. Moreover, the U.S. government has banned the production and use of certain dangerous pollutants such as DDT and PCBs.
In addition, two major changes have been introduced in the handling of sewage. First, smaller, less efficient sewage treatment plants are being replaced with modern, regional plants that include biological treatment, in which microorganisms are used to break down organic matter in the sewage. The newer plants are releasing much cleaner discharges into the receiving bodies of water (rivers, lakes, and ocean).
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A researcher inspects a soil core from a specially constructed wetland. The soil contains microbes that improve water quality by breaking down pesticides and removing nitrates.
Second, many jurisdictions throughout the United States are building separate sewer lines for storm water and sanitary wastes. These upgrades are needed because excess water in the older, "combined" sewer systems would simply bypass the treatment process, and untreated sewage would be discharged directly into receiving bodies of water.
To minimize pollutants from nonpoint sources, the EPA is requiring all municipalities to address the problem of runoff from roads and parking lots. At the same time, the use of fertilizers and pesticides needs to be reduced. Toward this end, county extension agents are educating farmers and homeowners about their proper application and the availability of nutrient testing.
To curtail the use of expensive and potentially harmful pesticides, the approach known as integrated pest management can be implemented [see "Safer Modes of Pest Control," The World & I, May 2000, p. 164]. It involves the identification of specific pest problems and the use of nontoxic chemicals and chemical-free alternatives whenever possible. For instance, aphids can be held in check by ladybug beetles and caterpillars can be controlled by applying neem oil to the leaves on which they feed.
Moreover, new urban development projects in many areas are required to implement storm-water management practices. They include such features as: oil and grease traps in storm drains; swales to slow down runoff, allowing it to infiltrate back into groundwater; "wet" detention basins (essentially artificial ponds) that allow solids to settle out of runoff; and artificial wetlands that help break down contaminants in runoff. While such additions may be costly, they significantly improve water quality. They are of course much more expensive to install after those areas have been developed.
Once a waterway is polluted, cleanup is often expensive and time consuming. For instance, to increase the concentration of dissolved oxygen in a lake that has undergone
eutrophication, fountains and aerators may be necessary. Specially designed boats may be needed to harvest nuisance weeds.
At times, it is costly just to identify the source of a problem. For example, if a body of water contains high levels of coliform bacteria, expensive DNA testing may be needed to determine whether the bacteria came from leakage of human sewage, pet waste, or the feces of waterfowl or other wildlife.
Contaminated sediments are sometimes difficult to treat. Available techniques range from dredging the sediments to "capping" them in place, to limit their potential exposure. Given that they act as reservoirs of pollutants, it is often best to remove the sediments and burn off the contaminants. Alternatively, the extracted sediments may be placed in confined disposal areas that prevent the pollutants from leaching back into groundwater. Dredging, however, may create additional problems by releasing pollutants back into the water column when the sediment is stirred up.
The future of clean water
he EPA reports that as a result of the Clean Water Act, millions of tons of sewage and industrial waste are being treated before they are discharged into U.S. coastal waters. In addition, the majority of lakes and rivers now meet mandated water quality goals.
Yet the future of federal regulation under the Clean Water Act is unclear. In 2001, a Supreme Court decision (Solid Waste Agency of Northern Cook County v. United States Army Corps of Engineers, et al.) brought into question the power of federal agencies to regulate activities affecting water quality in smaller, nonnavigable bodies of water. This and related court decisions have set the stage for the EPA and other federal agencies to redefine which bodies of water can be protected from unregulated dumping and discharges under the Clean Water Act. As a result, individual states may soon be faced with much greater responsibility for the protection of water resources.
Worldwide, more than one billion people presently lack access to clean water sources, and over two billion live without basic sanitation facilities. A large proportion of those who die from water-related diseases are infants. We would hope that by raising awareness of these issues on an international level, the newly recognized right to clean water will become a reality for a much larger percentage of the world's population.
On the Internet
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2003: International Year of Freshwater (UN)
www.wateryear2003.org
Clean Water Act (EPA)
www.epa.gov/watertrai
Do's and Don't's Around the Home (EPA)
www.epa.gov/owow/nps/dosdont.html
Love Canal Collection (SUNY Buffalo)
ublib.buffalo.edu/libraries/projects/lovecanal
National Water-Quality Assessment Program (USGS)
water.usgs.gov/nawqa
Office of Water (EPA)
www.epa.gov/ow
The World's Water
www.worldwater.org
Joseph Orlins, professor of civil engineering at Rowan University in Glassboro, New Jersey, specializes in water resources and environmental engineering. Anne Wehrly is an attorney and freelance writer.
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